Exotic items are more effective than legendary and are very hard to find because they drop at a much higher difficulty. You got to play difficulty four or brutal difficulty challenge four, as shown in the image below.
In this guide, you will come to know how to get the Exotic Items in Marvel’s Avengers.
You have to play any of the yellow marked missions in the highest difficulty, like the lost avengers standing with 14 floors of utter mayhem and bosses and elites. It is very hard, but it gives you good loot as long as you can complete the missions to get a gear reward.
There will be elite enemies; you can kill them and get their legendaries. One of those elites will drop you an exotic piece of gear called My Marvelous Regalia, as shown in the image below.
You can farm your first exotic item as well. Much good gear drops from Elite Enemy Soldiers, so you need to find a mission with elite enemy soldiers because these will give you the best stuff to use. An enemy with a shield or a fire-adapted guy will drop a legendary or an exotic item when you are playing in the high difficulty.
